Melting kinetics, ultra-drawability and microstructure of nascent ultra-high molecular weight polyethylene powder

نویسندگان

چکیده

For the production of high-performance polyethylene fibers and tapes by ultra drawing, using solid-state processing disentangled nascent ultra-high molecular weight (UHMWPE), maximum draw ratio is an important design parameter, as it determines degree chain alignment and, therewith, properties final product. It would, therefore, be advantageous to have a fast scanning method estimate drawability reactor powders. In present work, melting behavior UHMWPE powder was studied differential calorimetry, followed isoconversional analysis evaluate apparent activation energy barrier for different grades level disentanglement. Powder samples were solid-sate processed into at elevated temperature. Ultra drawing these optimum temperature allowed evaluation ( λ max ) that determined entanglement density. The morphology lamellar structure small-angle X-ray scattering transmission electron microscopy analyses. A correlation between kinetics, microstructure observed all grades, suggesting can used screening ratio. • detailed kinetics superheating (UHMWPE) analyzed experimentally method. films pressed from powder, inversely proportional melting. found thickness.

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ژورنال

عنوان ژورنال: Polymer

سال: 2021

ISSN: ['1873-2291', '0032-3861']

DOI: https://doi.org/10.1016/j.polymer.2021.123633