Mechanism of oxidation of nitroethane by glucose oxidase.
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چکیده
منابع مشابه
Mechanism of oxidation of nitroethane by glucose oxidase.
The oxidation of nitroethane by glucose oxidase has been studied in detail and compared to the analogous reaction catalyzed by n-amino acid oxidase and to the behavior of sugar substrates of glucose oxidase. The overall stoichiometry of the reaction is nonintegral and incompletely understood. Although the major products are nitrite, acetaldehyde (P), and hydrogen peroxide, small amounts of nitr...
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چکیده هدف از این کار بررسی الکترواکسیداسیون کتکول و مشتقات آن در حضور 4-فنیل سمی کاربامازید بوده است اکسیداسیون کتکولها ترکیبات نا پایدار کینونها را تولید می کنند که این ترکیبات می تواند در واکنش مایکل بعنوان پذیرنده نوکلئوفیل عمل نمایند. در ادامه اکسایش کتکولهای (a-c1) را درحضور 4-فنیل سمی کاربامازید در محلول آب/استونیتریل (90/10)بوسیله ولتامتری چرخه ای و کولن متری در پتانسیل ثابت مورد بررسی ...
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ژورنال
عنوان ژورنال: Journal of Biological Chemistry
سال: 1977
ISSN: 0021-9258
DOI: 10.1016/s0021-9258(17)40273-0