Mechanism of Cobalt-Catalyzed CO Hydrogenation: 1. Methanation
نویسندگان
چکیده
منابع مشابه
Mechanism of Cobalt-Catalyzed CO Hydrogenation: 1. Methanation
The mechanism of CO hydrogenation to CH4 at 260 °C on a cobalt catalyst is investigated using steady-state isotopic transient kinetic analysis (SSITKA) and backward and forward chemical transient kinetic analysis (CTKA). The dependence of CH x residence time is determined by 12CO/H2 → 13CO/H2 SSITKA as a function of the CO and H2 partial pressure and shows that the CH4 formation rate is mainly ...
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ژورنال
عنوان ژورنال: ACS Catalysis
سال: 2017
ISSN: 2155-5435,2155-5435
DOI: 10.1021/acscatal.7b02757