Marine gas-phase sulfur emissions during an induced phytoplankton bloom

نویسندگان

چکیده

Abstract. The oxidation of dimethyl sulfide (DMS; CH3SCH3), emitted from the surface ocean, contributes to formation Aitken mode particles and their growth cloud condensation nuclei (CCN) sizes in remote marine environments. It is not clear whether other less commonly measured marine-derived, sulfur-containing gases share similar dynamics DMS contribute secondary aerosol formation. Here, we present measurements gas-phase volatile organosulfur molecules taken with a Vocus proton-transfer-reaction high-resolution time-of-flight mass spectrometer during mesocosm phytoplankton bloom experiment using coastal seawater. We show that DMS, methanethiol (MeSH; CH3SH), benzothiazole (C7H5NS) account for on average over 90 % total sulfur emissions, non-DMS sources representing 36.8 ± 7.7 emissions first 9 d pre-bloom phase prior major biological growth, before declining 14.5 6.0 latter half when dominates decay phases. molar ratio MeSH (DMS : = 4.60 0.93) was consistent range previously calculated ambient DMS-to-MeSH sea-to-air flux ratios. As progressed, emission increased significantly, reaching 31.8 18.7 decay. Measurements dimethylsulfoniopropionate (DMSP), heterotrophic bacteria, enzyme activity seawater suggest sensitive indicator bacterial demand composition magnitude available evolving new precursor gas, benzothiazole, have important implications sulfate pathways

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ژورنال

عنوان ژورنال: Atmospheric Chemistry and Physics

سال: 2022

ISSN: ['1680-7316', '1680-7324']

DOI: https://doi.org/10.5194/acp-22-1601-2022