Magnesium hydride for energy storage applications: The kinetics of dehydrogenation under different working conditions
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منابع مشابه
Contamination Effects on Improving the Hydrogenation/Dehydrogenation Kinetics of Binary Magnesium Hydride/Titanium Carbide Systems Prepared by Reactive Ball Milling
Ultrafine MgH₂ nanocrystalline powders were prepared by reactive ball milling of elemental Mg powders after 200 h of high-energy ball milling under a hydrogen gas pressure of 50 bar. The as-prepared metal hydride powders were contaminated with 2.2 wt. % of FeCr-stainless steel that was introduced to the powders upon using stainless steel milling tools made of the same alloy. The as-synthesized ...
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Storage of hydrogen is one of the key challenges in developing hydrogen economy. Magnesium hydride (MgH2) is an attractive candidate for solid-state hydrogen storage for on-board applications. In this study, 10 wt.% ZrB2 was co-milled with magnesium hydride at different milling times to produce nanocrystalline composite powder. The effect of milling time and additive on the hydrogen desorption...
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Reversibility of a dehydrogenation/hydrogenation catalytic reaction has been an elusive target for homogeneous catalysis. In this report, reversible acceptorless dehydrogenation of secondary alcohols and diols on iron pincer complexes and reversible oxidative dehydrogenation of primary alcohols/reduction of aldehydes with separate transfer of protons and electrons on iridium complexes are shown...
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Highly crumpled graphene nanosheets (GNS) with a BET surface area as high as 1159 m(2) g(-1) was fabricated by a thermal exfoliation method. A systematic investigation was performed on the hydrogen sorption properties of MgH(2)-5 wt% GNS nanocomposites acquired by ball-milling. It was found that the as-synthesized GNS exhibited a superior catalytic effect on hydrogenation/dehydrogenation of MgH...
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ژورنال
عنوان ژورنال: Journal of Alloys and Compounds
سال: 2016
ISSN: 0925-8388
DOI: 10.1016/j.jallcom.2016.04.191