LX.—Estimation of primary, secondary, and tertiary amines. Part I

Gold(I) Complexes of Secondary and Tertiary Amines. Crystal Structure of Triphenylphosphineaurio(I)quinuclidinium Tetrafluoroborate

The secondary amine piperidine and the tertiary amine quinuclidine (l-azabicyclo[2.2.2]octane) were reacted in THF with one equivalent of triphenylphosphinegold(I) tetrafluoro­ borate, [Ph3PAu]+ BF4“, to give the monoaurated ammonium salts of formula [R„NHp_„)AuPPh3]+ BF4~ (n = 2, 3). The compounds were obtained as crystalline solids in good yields, and were characterized by IR and NM R spectro...

Equilibrium and Transport Properties of Primary, Secondary and Tertiary Amines by Molecular Simulation

Equilibrium and Transport Properties of Primary, Secondary and Tertiary Amines by Molecular Simulation — Using molecular simulation techniques such as Monte-Carlo (MC) and molecular dynamics (MD), we present several simulation results of thermodynamic and transport properties for primary, secondary and tertiary amines. These calculations are based on a recently proposed force field for amines t...

Efficient metal-free hydrosilylation of tertiary, secondary and primary amides to amines.

Hydrosilylation of secondary and tertiary amides to amines is described using catalytic amounts of B(C6F5)3. The organic catalyst enables the reduction of amides with cost-efficient, non-toxic and air stable PMHS and TMDS hydrosilanes. The methodology was successfully extended to the more challenging reduction of primary amides.

General preparation of primary, secondary, and tertiary aryl amines by the oxidative coupling of polyfunctional aryl and heteroaryl amidocuprates.

Calculation of the Proton Affinities of Primary, Secondary, and Tertiary Amines Using Semiempirical and ab initio Methods

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