Looking inside an endohedral fullerene: Inter- and intramolecular ordering ofDy3N@C80(Ih)on Cu(111)
نویسندگان
چکیده
منابع مشابه
Fullerene C60 as an endohedral molecule within an inorganic supramolecule.
The synthesis and properties of large spherical molecules and giant clusters is a fascinating field in contemporary chemistry, unifying all areas of organic/supramolecular, inorganic, and coordination chemistry as well as organometallic chemistry. Recent developments of low-valent group 13 metalloid clusters,1 chalcogeno-bridged copper, and silver clusters2 as well as giant polyoxomolybdates3 r...
متن کاملPhotoionization of the endohedral fullerene ions
The first experimental results on photoionization of mass-selected endohedral Sc3N@C + 80 and Ce@C + 82 fullerene ions are reported. The merged-beams technique was employed to measure photo-ion yield spectra as well as absolute cross sections. Comparing the results of endohedral fullerenes with those obtained using ”empty” C+80 and C + 82 ions provides insight into the mutual influence of the f...
متن کاملCryogenic NMR spectroscopy of endohedral hydrogen-fullerene complexes.
We have observed 1H NMR spectra of hydrogen molecules trapped inside modified fullerene cages under cryogenic conditions. Experiments on static samples were performed at sample temperatures down to 4.3 K, while magic-angle-spinning (MAS) experiments were performed at temperatures down to 20 K at spinning frequencies of 15 kHz. Both types of NMR spectra show a large increase in the intramolecula...
متن کاملSublimation of the endohedral fullerene Er(3)N@C(80).
The heat of sublimation of the endohedral metallofullerene Er(3)N@C(80) was measured via Knudsen effusion mass spectrometry. The large molecule consists of a C(80) fullerene cage which is stabilized by a complex of three erbium atoms bounded to a nitrogen atom and has a mass of 1475 amu. The mass spectrum at a temperature of 1045 K and the relative intensities of the thermal fractions of Er(3)N...
متن کاملSolid-state NMR of endohedral hydrogen-fullerene complexes.
We present an overview of solid-state NMR studies of endohedral H(2)-fullerene complexes, including (1)H and (13)C NMR spectra, (1)H and (13)C spin relaxation studies, and the results of (1)H dipole-dipole recoupling experiments. The available data involves three different endohedral H(2)-fullerene complexes, studied over a wide range of temperatures and applied magnetic fields. The symmetry of...
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ژورنال
عنوان ژورنال: Physical Review B
سال: 2009
ISSN: 1098-0121,1550-235X
DOI: 10.1103/physrevb.80.081403