Living Polymerization of Propylene with ansa-Dimethylsilylene(fluorenyl)(cumylamido) Titanium Complexes

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Living Polymerization of Propylene with ansa-Dimethylsilylene(fluorenyl)(cumylamido) Titanium Complexes

A series of ansa-silylene(fluorenyl)(amido) titanium complexes (1a–1c, 2a, and 2b) bearing various substituents on the amido and fluorenyl ligands are synthesized and characterized by elemental analysis, 1H NMR, and single crystal X-ray analysis. The coordination mode of the fluorenyl ligand to the titanium metal is η3 manner in each complex. The propylene polymerization is conducted with these...

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ژورنال

عنوان ژورنال: Polymers

سال: 2017

ISSN: 2073-4360

DOI: 10.3390/polym9040131