Liposomes Can Achieve Enantioselective C–C Bond Formation of an α-Amino Acid Derivative in Aqueous Media
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An Electrochemical Study of the S-Derivatives of 2-Amino Cyclopentene-1-Dithiocharboxylic Acid in Aqueous Ethanolic Media
A systematic study on the electrochemical behavior of the S-derivatives of 2-amino cyclopentene-1-dithiocarboxylic acid (ACDA) has been carried out in aqueous ethanolic solutions by means of polarography, coulometry and voltammetry. All the compounds studied exhibited a well defined anodic wave corresponding to a diffusion controlled process. Controlled potential coulometry gave n=1 per mol...
متن کاملan electrochemical study of the s-derivatives of 2-amino cyclopentene-1-dithiocharboxylic acid in aqueous ethanolic media
a systematic study on the electrochemical behavior of the s-derivatives of 2-amino cyclopentene-1-dithiocarboxylic acid (acda) has been carried out in aqueous ethanolic solutions by means of polarography, coulometry and voltammetry. all the compounds studied exhibited a well defined anodic wave corresponding to a diffusion controlled process. controlled potential coulometry gave n=1 per mole fo...
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Formation of non bonded organic layer around inorganic particles like iron sulfide and zeolites, was hypothesized as starting point for one of the possible mechanisms of the origin of life on earth. In this study, the general circumstances needed for creation of such organic layer was investigated. An aliphatic hydrocarbon (hexane), an aromatic hydrocarbon (toluene), an alcohol (n-octanol) and ...
متن کاملEnantioselective Synthesis of D-α-Amino Amides from Aliphatic Aldehydes.
Peptides consisting of D-amino amides are highly represented among both biologically active natural products and non-natural small molecules used in therapeutic development. Chemical synthesis of D-amino amides most often involves approaches based on enzymatic resolution or fractional recrystallization of their diastereomeric amine salts, techniques that produce an equal amount of the L-amino a...
متن کاملSynthesis of arylidinebarbituric acid derivatives catalyzed by dodecylbenzenesulfonic acid (DBSA) in aqueous media
A series of arylidine barbituric acid derivatives was synthesized by Knoevenagel condensation reaction of aromatic aldehydes with barbituric acid or thiobarbituric acid using dodecylbenzenesulfonic acid as a Brønsted acid-surfactant catalyst in aqueous media. Regardless of the nature of the substitution (electron-donating and -withdrawing), all the reactions were completed within 15-65 min in w...
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ژورنال
عنوان ژورنال: ACS Omega
سال: 2017
ISSN: 2470-1343,2470-1343
DOI: 10.1021/acsomega.6b00479