Lignans and Polyacetylenes fromBupleurumacutifolium
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چکیده
منابع مشابه
Lignans and polyacetylenes from bupleurum acutifolium
Two new lignans (R,Z)-3-(3,4-dimethoxybenzyl)-2-(3, 4-dimethoxybenzylidene)-gamma-butyrolactone (1) and (2R, 3S)-2-acetoxy-2,3-bis(3,4-dimethoxybenzyl)-gamma-butyrolactone (2), and four new polyacetylenes, (2Z,8E,10E)-heptadeca-2,8,10-triene-4, 6-diyn-1-ol (3), (2E,9Z)-octadeca-2,9-diene-4,6-diyne-1,18-diol (4), (2E,9Z)-18-hydroxy-octadeca-2,9-diene-4,6-diyn-1-yl acetate (5), and (2E,9Z)-1-hydr...
متن کاملLignans, phenylpropanoids and polyacetylenes from Chaerophyllum aureum L. (Apiaceae).
Sub-aerial parts of Chaerophyllum aureum L. yielded two polyacetylenes, falcarinol (1), falcarindiol (2), three lignans, namely nemerosin (3), deoxypodorhizone (4), deoxypodo-phyllotoxin (5), two phenylpropanoids, 1'-hydroxymyristicin (6) and its angeloyl ester (7). Compounds 6 and 7 were isolated for the first time from plant material and their structures were elucidated by means of extensive ...
متن کاملThe Biosynthesis of Polyacetylenes
The principal acetylenic metabolites of the basidiomycete B. 841 (probably a Poria sp.) are known to be the hydroxy acids nemotinic acid (I) and odyssic acid (II), together with derivatives such as the corresponding lactones (Bu'Lock, Jones & Leeming, 1955, 1957). Acetylenic compounds of various kinds are now known to be relatively common constituents of certain groups of plants and fungi, and ...
متن کاملSaturation of the second hyperpolarizability for polyacetylenes
Polyacetylene (PA) polymers -(-CH=CH-), lead to large second hyperpolarizabilities (y) that increase with N. For small N the increase is quite rapid, eventually saturating (becoming linear in N) for N > N& Both experimental and theoretical attempts have been made to estimate N,Y,,. In 1994 this led to two Science papers, one obtaining NA, = 20 (semiempirical theory) and the other obtaining N,,,...
متن کاملLignans from Kadsura angustifolia.
A new dibenzocyclooctadiene lignan named angustifolin D (1) together with four known lignans: kadsulignan L (2), kadsulignan N (3), schisantherin P (4) and meso-dihydroguaiaretic acid (5) were isolated from the stems of Kadsura angustifolia. Their structures and stereochemistries were elucidated by spectral studies. Compounds 2 and 5 showed moderate platelet-activating factor (PAF) antagonistic...
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ژورنال
عنوان ژورنال: Journal of Natural Products
سال: 1999
ISSN: 0163-3864,1520-6025
DOI: 10.1021/np980445p