Ligand- and oxygen-isotope-exchange pathways of geochemical interest
نویسندگان
چکیده
منابع مشابه
Mass-independent Isotope Fractionation of Chromium in Ligand Exchange
Introduction: Recently, the classic theory of stable isotope fractionation of the Bigeleisen-Mayer equation [1] has been expanded by the original author to include the mass-independent term named the nuclear field shift effect [2]. The improved theory successfully explained the observed non-linear isotope effect on U in a chemical exchange system [2]. Since then, researchers have applied the ne...
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polarization causes Q1ftf partly to cance12 Qu' and so to reduce the calculated MO approximation DNQ, making it agree better with the observed value.2~ This improvement most probably much outweighs the contrary effects obtained by optimizing Z*. The effect on DNQ of using polarized AO's is quite different in the AO than in the MO approximation. Referring to an earlier paragraph on the variation...
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ژورنال
عنوان ژورنال: Environmental Chemistry
سال: 2015
ISSN: 1448-2517
DOI: 10.1071/en14043