Kinetically Stabilized Organophosphorus Radicals
نویسندگان
چکیده
منابع مشابه
Resonance stabilized bis-thiadiazinyl radicals.
The resonance stabilized bis-thiadiazinyl framework holds potential as a stable and versatile building block for the design of radical-based conductors and magnetic materials.
متن کاملKinetically stabilized dibenzoborole as an electron-accepting building unit.
A synthetic route to a dibenzoborole, kinetically stabilized by the 2,4,6-tri-tert-butylphenyl group, was developed, and a series of pi-extended derivatives were synthesized, which show orange-red emissions and stable electrochemical redox properties.
متن کاملKinetically stabilized aliovalent europium-doped magnesium oxide as a UV sensitized phosphor.
Doping of size mismatched aliovalent ions is challenging due to the associated elastic and electronic stress making the thermodynamics unfavorable. Despite such features, its utilization may be viable if such systems can be made metastable by suppressing the kinetics of phase segregation. In light of such a possibility, we utilize sol-gel synthesis for preparing a size mismatched trivalent euro...
متن کاملGlobal energy confinement scaling predictions for the kinetically stabilized tandem mirror
Transport is studied for the kinetically stabilized tandem mirror, an attractive magnetic confinement device for achieving a steady-state burning plasma. For a magnetohydrodynamic stable system, three different radial transport models with Bohm, gyro-Bohm, and electron temperature gradient ETG scaling are derived. As a conservative estimate, numerical coefficients in the models are taken to be ...
متن کاملReactivity of certain organophosphorus insecticides toward hydroxyl radicals at elevated air temperatures.
Methods were developed to determine OH reaction rates for medium-weight organophosphorus pesticides in the gas phase. A 57-L chamber was constructed that utilized xenon arc irradiation (>290 nm) to photolyze the OH precursor, methyl nitrite. Experiments were performed at elevated temperatures ranging from 60 to 80 degrees C to minimize wall sorption. Solid-phase microextraction (SPME) sampling ...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Journal of Synthetic Organic Chemistry, Japan
سال: 2015
ISSN: 0037-9980,1883-6526
DOI: 10.5059/yukigoseikyokaishi.73.276