Isomerization of glucose to fructose catalyzed by metal–organic frameworks
نویسندگان
چکیده
High catalytic activity is found to be due the combination of a chromium catalyst with large pores (MIL-101(Cr)) aprotic solvents (γ-valerolactone−10% H2O).
منابع مشابه
Isomerization of Glucose to Fructose
In the previous paper, one of the authors described "A Survey on the Dextrose Industry in Japan and its Future" in the 1967 issue. As shown in the earlier paper, the supply and demand situation of starch in this country was drastically changed since 1963-64. In the later 1950's, the Japanese Government had a big problem to eliminate the big stock of the over-produced sweet potato starch. Theref...
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Catalytic isomerization of glucose to fructose by immobilized glucose isomerase in an aqueous-ethanol medium was studied. Using Michaelis-Menten equation and Haldane relationship, the main kinetic parameters were determined: Kmf, Vmf, Kmr, Vmr. By comparing the aqueous-ethanol medium with an aqueous solution, the measured values of Kmr and Kmf were increased in the aqueous-ethanol solution, whi...
متن کاملDetermination of Kinetic Parameters for Catalytic Isomerization of Glucose to Fructose by immobilized Glucose Isomerase in an Aqueous-Ethanol Medium
Catalytic isomerization of glucose to fructose by immobilized glucose isomerase in an aqueous-ethanol medium was studied. Using Michaelis-Menten equation and Haldane relationship, the main kinetic parameters were determined: Kmf, Vmf, Kmr, Vmr. By comparing the aqueous-ethanol medium with an aqueous solution, the measured values of Kmr and Kmf were increased in the aqueous-ethanol solution, whi...
متن کاملdetermination of kinetic parameters for catalytic isomerization of glucose to fructose by immobilized glucose isomerase in an aqueous-ethanol medium
catalytic isomerization of glucose to fructose by immobilized glucose isomerase in an aqueous-ethanol medium was studied. using michaelis-menten equation and haldane relationship, the main kinetic parameters were determined: kmf, vmf, kmr, vmr. by comparing the aqueous-ethanol medium with an aqueous solution, the measured values of kmr and kmf were increased in the aqueous-ethanol solution, whi...
متن کاملGeneralized linearization of kinetics of glucose isomerization to fructose by immobilized glucose isomerase.
The kinetic parameters of both glucose isomerization to fructose and immobilized glucose isomerase (GI) inactivation calculated under different conditions are compared and discussed. Utilizing these figures, the possibility of generalizing a linear model, previously proposed for the kinetics of glucose isomerization by immobilized glucose isomerase, is investigated, so as to apply them to whole...
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ژورنال
عنوان ژورنال: Sustainable Energy and Fuels
سال: 2021
ISSN: ['2398-4902']
DOI: https://doi.org/10.1039/d1se00771h