Isolable Phosphanylidene Phosphorane with a Sterically Accessible Two-Coordinate Phosphorus Atom
نویسندگان
چکیده
منابع مشابه
Isolable Phosphanylidene Phosphorane with a Sterically Accessible Two-Coordinate Phosphorus Atom**
Phosphanylidene-s-phosphoranes (RP=PR’3) are phosphorus analogues of alkylidene-s-phosphoranes (R2C=PR’3), better known as Wittig reagents. Phosphanylidene-s-phosphoranes are synthetically accessible in the free form (RP= PR’3) and also in the transition-metal-stabilized form (LnM !P(R)=PR’3). [1] The latter complexes are commonly used in both P=C bond generation and as a source of the phosphin...
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ژورنال
عنوان ژورنال: Angewandte Chemie International Edition
سال: 2012
ISSN: 1433-7851
DOI: 10.1002/anie.201204998