Iron oxide catalyzed reduction of acid chlorides to aldehydes with hydrosilanes
نویسندگان
چکیده
منابع مشابه
Nickel(0)-catalyzed intramolecular reductive coupling of alkenes and aldehydes or ketones with hydrosilanes.
A nickel(0)-catalyzed reductive coupling of aldehydes and simple alkenes with hydrosilanes has been developed. A variety of silyl-protected 1-indanol derivatives were prepared in a highly diastereoselective manner (up to >99 : 1 dr) by employing a combination of nickel(0)/N-heterocyclic carbene and triethylsilane. The present system was also applied to a reductive coupling with ketones. Prelimi...
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ژورنال
عنوان ژورنال: Catalysis Communications
سال: 2014
ISSN: 1566-7367
DOI: 10.1016/j.catcom.2014.02.018