منابع مشابه
lon molecule reactions in vinyl fluoride by photoionization . Effects of vibrational excitation on major reaction pathways *
Photoionization methods have been used to study the reactions of the molecular ion in vinyl fluoride to yield the ionic products C3H 3F{, C3H 4F+, and C3Ht. Quantitative measurements are reported of the effect of the vibrational state of the reactant ion on the product distribution and overall reaction cross section. Reaction cross sections for all three channels decrease with reactant internal...
متن کاملSynthesis of alkynes from vinyl triflates using tetrabutylammonium fluoride.
A convenient method for the preparation of alkynes and alkynyl esters from ketones and β-keto esters is described which involves the formation of vinyl triflates, followed by elimination with tetrabutylammonium fluoride trihydrate, to give alkynes. Unlike established elimination methods, the method requires neither a strong base nor anhydrous conditions.
متن کاملHigh stereoselectivity in chelation-controlled intermolecular Heck reactions with aryl chlorides, vinyl chlorides and vinyl triflates.
Highly stereoselective chelation-controlled Pd(0)-catalyzed beta-arylations and beta-vinylations of a five-membered chiral, pyrrolidine-based vinyl ether were achieved using aryl- and vinyl chlorides as substrates, yielding quaternary 2-aryl/vinyl-2-methyl cyclopentanones in 89-96% ee under neutral reaction conditions.
متن کاملVinyl sulfone building blocks in covalently reversible reactions with thiols
In the present study we use quantum-chemical calculations to investigate how the reactivity of vinyl sulfone-based compounds can be modified from an irreversible to a reversible reaction with thiols. Based on the predictions from theory, an array of nine different vinyl sulfones with systematically varying substitution pattern was synthesized and their crystal structures were determined. Subseq...
متن کاملReactions of vinyl ethers with cobalamins and cobaloximes.
Sir: We recently reported 1 that cobaloximes and cobalamins reacted with vinyl ethers, in the presence of alcohols, to give aceta Is containing cobalt-carbon cr-bonds. On the basis of these, and earlier 2 experiments, we suggested that the reactions proceeded via the intermediary of a Co(lII)-olefin 7r-complex. Schrauzer, et al.,3 then reported that they were unable to confirm our results and c...
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ژورنال
عنوان ژورنال: Canadian Journal of Chemistry
سال: 1969
ISSN: 0008-4042,1480-3291
DOI: 10.1139/v69-153