Ion track grafting: A way of producing low-cost and highly proton conductive membranes for fuel cell applications
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چکیده
منابع مشابه
Ion track grafting: A way of producing low-cost and highly proton conductive membranes for fuel cell applications
Proton conductive individual channels through a PVDF matrix have been designed using the ion track grafting technique. The chosen polyelectrolyte, a sulfonated polystyrene (PSSA), has been radiografted all along the linear and cylindrical ion tracks of irradiated PVDF leading to the creation of privileged paths for proton conduction from the anode to the cathode without inducing any further por...
متن کاملStudies on the SPEEK membrane with low degree of sulfonation as a stable proton exchange membrane for fuel cell applications
Sulfonated poly (ether ether ketone) (SPEEK) with a low degree of sulfonation (DS = 40%) was prepared for proton exchange membrane fuel cells (PEMFC). Poly (ether ether ketone) (PEEK) was sulfonated in concentrated H2SO4 under N2 atmosphere and characterized by the hydrogen nuclear magnetic resonance (H-NMR) technique. After preparation of the SPEEK polymer, the obtained polymer was dissolved i...
متن کاملPreparation of anisotropically proton-conductive materials based on poly(vinylidene fluoride) ion track membranes
Proton exchange membranes (PEMs) for polymer electrolyte fuel cells (PEFCs) have recently been developed by our original techniques of the γ-ray or electron-beam crosslinking and graft polymerization. Our additional main focus is the use of cylindrical damage in polymers produced by bombardment of high-energy ions, that is called a latent track. We are taking the approach using this ion track t...
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A novel sulfonated poly(4-phenoxypropylbenzoyl-1,4-phenylene) introducing a flexible alkyl chain was synthesized and achieved high proton conductivity even at low humidity (SPP: 0.077 S cm(-1), Nafion 112: 0.029 S cm(-1) at 80 degrees C 50% RH).
متن کاملstudies on the speek membrane with low degree of sulfonation as a stable proton exchange membrane for fuel cell applications
sulfonated poly (ether ether ketone) (speek) with a low degree of sulfonation (ds = 40%) was prepared for proton exchange membrane fuel cells (pemfc). poly (ether ether ketone) (peek) was sulfonated in concentrated h2so4 under n2 atmosphere and characterized by the hydrogen nuclear magnetic resonance (h-nmr) technique. after preparation of the speek polymer, the obtained polymer was dissolved i...
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ژورنال
عنوان ژورنال: Journal of Power Sources
سال: 2010
ISSN: 0378-7753
DOI: 10.1016/j.jpowsour.2009.07.016