Ion specific effects: decoupling ion–ion and ion–water interactions

Ion Specific Hofmeister Effects Solution electrostatics beyond pH: a coarse grained approach to ion specific interactions between macromolecules

Ion-specific effects in foams.

We present a critical review on ion-specific effects in foams in the presence of added salts. We show the theoretical basis developed for understanding experimental data in systems with ionic surfactants, as well as the nascent approaches to modeling the much more difficult systems with non-ionic surfactants, starting with the most recent models of the air-water interface. Even in the case of i...

Specific ion effects via ion hydration: I. Surface tension.

A simple modality is suggested to include, in the framework of a modified Poisson-Boltzmann approach, specific ion effects via the change in the ion hydration between the bulk and the vicinity of the surface. This approach can account for both the depletion of the interfacial region of structure-making ions as well as for the accumulation of structure-breaking ions near the interface. Expressio...

Specific ion effects via ion hydration: II. Double layer interaction.

A simple modified Poisson-Boltzmann formalism, which accounts also for those interactions between electrolyte ions and colloidal particles not included in the mean potential, is used to calculate the force between two parallel plates. It is shown that the short-range interactions between ions and plates, such as those due to the change in the hydration free energy of a structure-making/breaking...

Specific Ion Effects in Cholesterol Monolayers

The interaction of ions with interfaces and, in particular, the high specificity of these interactions to the particular ions considered, are central questions in the field of surface forces. Here we study the effect of different salts (NaI, NaCl, CaCl₂ and MgCl₂) on monolayers made of cholesterol molecules, both experimentally (surface area vs. lateral pressure isotherms measured by a Langmuir...