Investigating a Redox Active Samarium Complex in Catalytic Reactions
نویسندگان
چکیده
Herein the synthesis of a new ethynyl ferrocenyl amidinate ligand [Fc?C?C-{C(Ndipp)$_{2}$H}] (Fc=ferrocenyl; dipp=diisopropylphenyl) and subsequent formation corresponding samarium amido complex [Sm{Fc?C?C-[C(Ndipp)$_{2}$$_{2}$]}$_{2}${N(SiMe$_{3}$3)$_{2}$}] is reported. [Fc?C?C-{C(Ndipp)2H}] [Sm{Fc?C?C-[C(Ndipp)$_{2}$]}$_{2}${N(SiMe$_{3}$)$_{2}$}] were fully characterized including study complex’ redox properties by cyclovoltammetry. Furthermore, we investigated catalytic in intramolecular hydroamination reaction intermolecular dehydrocoupling pinacol borane with various amines.
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ژورنال
عنوان ژورنال: European Journal of Inorganic Chemistry
سال: 2021
ISSN: ['1434-1948', '1099-0682']
DOI: https://doi.org/10.1002/ejic.202100391