Inorganic chemical biology: from small metal complexes in biological systems to metalloproteins
نویسندگان
چکیده
منابع مشابه
Transition metal peroxo complexes relevant to metalloproteins
ABSTRACT A series of dioxygen complexes of copper, iron, and manganese have been synthesized using bulky tripodal nitrogen ligands, hydrotris(3,5-dialkyl1-pyrazolyl)borate, as models for the active sites in the metalloproteins. A binuclear copper peroxo complex having p-q2:$ coordination mode serves as an accurate model of the active site of oxy-hemocyanin. The reactivities of the complex and r...
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ژورنال
عنوان ژورنال: Current Opinion in Chemical Biology
سال: 2008
ISSN: 1367-5931
DOI: 10.1016/j.cbpa.2008.03.008