Improving Aqueous Biphasic Hydroformylation of Unsaturated Oleochemicals Using a Jet‐Loop‐Reactor
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چکیده
منابع مشابه
Hydroformylation of Unsaturated Fatty Acids
When hydroformylation of unsaturated fatty materials is done with rhodiu~-tripheny:lphosphine (or phosphite) catalysts, a number of advantages become apparent compared to cobalt carbonyl-catalyzed reactions. With rhodium, the reaction can be carried out (a) at pressures as low as 200 psi, (b) at each double bond location in a polyunsaturated fatty acid, and (c) in high yield and conversion. Sol...
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Mixtures of randomly methylated cyclodextrins of various sizes have been evaluated in the rhodium-catalysed hydroformylation of higher olefins in an aqueous biphasic medium. A marked positive non-linear effect on 1-tetradecene conversion is observed when the CD molar ratio in the mixture is modified. The formation of 2:1 ternary inclusion complexes between RAME-CDs and the olefin is supposed to...
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Two cobalt-carbonyl oxo processes were developed to prepare useful products in high yield from fatty derivatives. In one process, hydroformylation in the presence of MeOH at 120 C gives dimethyl acetal esters from either methyl oleate or oleic acid. In the other, a two-step process, hydroformylation (120 C) followed by hydrogenation (180 C) gives better yields of hydroxY methyl esters from both...
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Biphasic hydroformylation of 1-octene was performed using rhodium sulfoxantphos catalyst dissolved in [BuPy][BF4] ionic liquid. Preliminary experiments proved this system to retain the catalytic complex within the ionic liquid phase and to maintain a high selectivity towards the linear aldehyde (n:iso ratio of 30) over several cycles. Process parameter investigation showed a first order depende...
متن کاملRecoverable and recyclable water-soluble sulphonated salicylaldimine Rh(I) complexes for 1-octene hydroformylation in aqueous biphasic media.
A series of water-soluble Rh(i) mononuclear complexes of general formula: [Rh(sulphsal-X-R)(COD)] [sulphsal = sulphonated salicylaldimine, COD = cyclooctadiene; where R = H, Cl, CH3 and X = H, (t)Bu] have been synthesized. All the compounds were characterised using various spectroscopic and analytical techniques such as nuclear magnetic resonance spectroscopy, infrared spectroscopy, single crys...
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ژورنال
عنوان ژورنال: European Journal of Lipid Science and Technology
سال: 2019
ISSN: 1438-7697,1438-9312
DOI: 10.1002/ejlt.201900166