Identifying the high entropy characteristic in La-based metallic glasses

Pronounced slow β-relaxation in La-based bulk metallic glasses.

Most metallic glasses (MGs) exhibit weak evidence of slow β-relaxation in their dynamic mechanical spectroscopy spectra. In contrast to other MGs, the La-based MGs we report here show a distinct slow β-relaxation peak in the mechanical relaxation measurements. We find that the slow β-relaxation behavior can be tuned by modification of the chemical composition and fragility. The structural origi...

High-frequency dynamics in metallic glasses.

Using inelastic x-ray scattering we studied the collective dynamics of the glassy alloy Ni33Zr67 in the first pseudo-Brillouin-zone, an energy-momentum region still unexplored in metallic glasses. We determine key properties such as the momentum transfer dependence of the sound velocity and of the acoustic damping, discussing the results in the general context of recently proposed pictures for ...

OXYGEN DISTRIBUTION IN Zr-BASED METALLIC GLASSES

This paper reports the atom probe analysis results of the oxygen dissolved in the as-cast amorphous and crystallized Zr65Cu15Al10Pd10 and Zr65Cu17.5Ni10Al7.5 alloys. Impurity oxygen ranging from 0.1 to 1 at.% is dissolved uniformly in the as-quenched Zr65Cu15Al10Pd10 and Zr65Cu17.5Ni10Al7.5 amorphous alloys even though the oxygen is not added intentionally. When the Zr65Cu15Al10Pd10 alloy is cr...

Microstructure of fragile metallic glasses inferred from ultrasound-accelerated crystallization in Pd-based metallic glasses.

By utilizing ultrasonic annealing at a temperature below (or near) the glass transition temperature Tg, we revealed a microstructural pattern of a partially crystallized Pd-based metallic glass with a high-resolution electron microscopy. On the basis of the observed microstructure, we inferred a plausible microstructural model of fragile metallic glasses composed of strongly bonded regions surr...

Superconductivity in Metallic Glasses