Ideality in Context: Motivations for Total Synthesis
نویسندگان
چکیده
منابع مشابه
Toward ideality: the synthesis of (+)-kalkitoxin and (+)-hydroxyphthioceranic acid by assembly-line synthesis.
The iterative homologation of boronic esters using chiral lithiated benzoate esters and chloromethyllithium has been applied to the highly efficient syntheses of two natural products, (+)-kalkitoxin and (+)-hydroxyphthioceranic acid. The chiral lithiated benzoate esters (>99% ee) were generated from the corresponding stannanes, which themselves were prepared by Hoppe-Beak deprotonation of ethyl...
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ژورنال
عنوان ژورنال: Accounts of Chemical Research
سال: 2021
ISSN: 0001-4842,1520-4898
DOI: 10.1021/acs.accounts.0c00821