Icosahedral B12-containing core–shell structures of B80

Icosahedral B 12 - containing core – shell structures of B 80 w

B12Hn and B12Fn: planar vs icosahedral structures

Using density functional theory and quantum Monte Carlo calculations, we show that B12Hn and B12Fn (n = 0 to 4) quasi-planar structures are energetically more favorable than the corresponding icosahedral clusters. Moreover, we show that the fully planar B12F6 cluster is more stable than the three-dimensional counterpart. These results open up the possibility of designing larger boron-based nano...

Fed-Batch Production of a Fermented Beverage Containing Vitamin B12

Production of fermented functional foods containing micronutrients is required for their health beneficial properties. The impact of 11 process variables on vitamin B12 production in a dairy beverage containing propionic acid was investigated. Propionibacterium freudenreichii ssp. shermanii was applied in a 3-l fermentor in the fed-batch fermentation system. The most suitable conditions for...

DNA duplex cage structures with icosahedral symmetry

A construction method for duplex cage structures with icosahedral symmetry made out of single-stranded DNA molecules is presented and applied to an icosidodecahedral cage. It is shown via a mixture of analytic and computer techniques that there exist realisations of this graph in terms of two circular DNA molecules. These blueprints for the organisation of a cage structure with a noncrystallogr...

Local Density Functional Electronic Structures of Three Stable Icosahedral Fullerenes

a distinctive and general feature of gas-phase aromatic substitution, occurs only in those cases where the electrophile fulfils certain requirements. Paramount among the latter seem to be the presence of H atoms carrying a substantial fraction of the positive charge, capable of establishing localized H bonds with the unshared electrons of the substituent, as well as a suitable geometry of the c...