Hydration States and Blood Compatibility of Hydrogen-Bonded Supramolecular Poly(2-methoxyethyl acrylate)

Multiple Hydrogen-Bonded Supramolecular Polymers

Alternation and tunable composition in hydrogen bonded supramolecular copolymers.

Sequence control in supramolecular copolymers is limited by the selectivity of the associating monomer end groups. Here we introduce the use of monomers with aminopyrimidinone and aminohydroxynaphthyridine quadruple hydrogen bonding end groups, which both homodimerize, but form even stronger heterodimers. These features allow the formation of supramolecular copolymers with a tunable composition...

Hydrogen‐Bonded Macrocyclic Supramolecular Systems in Solution and on Surfaces

Cyclization into closed assemblies is the most recurrent approach to realize the noncovalent synthesis of discrete, well-defined nanostructures. This review article particularly focuses on the noncovalent synthesis of monocyclic hydrogen-bonded systems that are self-assembled from a single molecule with two binding-sites. Taking advantage of intramolecular binding events, which are favored with...

Hydrogen-Bonded Porphyrinic Solids: Supramolecular Networks of Octahydroxy Porphyrins

Symmetrically substituted octahydroxy porphyrins, tetrakis(3′,5′-dihydroxyphenyl)porphyrin, H2T(3′,5′DHP)P, tetrakis(2′,6′-dihydroxyphenyl)porphyrin, H2T(2′,6′-DHP)P, and their Zn(II) and Mn(III) derivatives have been developed as building blocks for supramolecular hydrogen-bonded networks. The crystal structures of a series of these porphyrins exhibit unique structural features through assembl...

Hydrogen bonded supramolecular polymers in moderately polar solvents.

Hydrogen bonded assemblies are usually decomposed by polar organic solvents. However, we have succeeded in preparing a strongly associated supramolecular polymer which forms viscous solutions in competitive solvents such as tetrahydrofuran.