Humic acids from lignite. 2. Alkaline permanganate oxidation
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چکیده
منابع مشابه
Humic acids from lignite. 2. Alkaline permanganate oxidation
The potassium permanganate oxidation of methylated humic acid from a Spanish lignite yielded mainly straight-chain alkanes together with a mixture of fatty acids, methyl straight-chain alkyl ketones, aliphatic dicarboxylic, phenolic and benzenecarboxylic acids. Furthermore, some unusual compounds such as dehydroabietic and bromohydroxybenzoic acids and bis(2-ethylhexyl)phthalate were also ident...
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Humic substances, i.e. dark paramagnetic polymeric anionic polyelectrolytes, belong to the most widespread macromolecular substances of biogenic origin in soil and aquatic environments. The exact structure of humic substances is unknown because of their complexity resulting from unrecurring precursors, from their composition and their process of synthesis. Degradation processes of these substan...
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Permanganate oxidation of benzaldehyde and p-nitrobenzaldehyde goes by two paths, i.e. a major one which is responsible for the normal oxidation giving good second order kinetic and minor path which involves a very small percent of a radical species formed by hydrogen atom abstraction by the permanganate ion. A mechanism involving Hydrogen atom abstraction by permanganate from the alkoxide ion ...
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A lignite humic acid (HA) was fractionated by preparative high performance size-exclusion chromatography (HPSEC) in seven different size-fractions. The size-fractions were characterized by cross polarization (CP) magic angle spinning (MAS) (13)C NMR spectroscopy and a further analytical HPSEC elution under UV and fluorescence detection. The alkyl hydrophobic components mainly distributed in the...
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ژورنال
عنوان ژورنال: Fuel
سال: 1978
ISSN: 0016-2361
DOI: 10.1016/0016-2361(78)90172-2