Highly saturated nitrile elastomer (hydrogenated NBR).

Thermal and Morphological Properties of Thermoplastic Elastomer Nanocomposites Based on PA6/NBR

Highly enantioselective metallation-substitution alpha to a chiral nitrile.

We report the deprotonation of a chiral nitrile and reaction of the resulting chiral organometallic species with a variety of electrophiles to give highly enantiomerically enriched 2-substituted nitrile products. The nitrile was treated with TMPMgCl and the resulting anion, an asymmetric alpha cyano Grignard species, was found to be configurationally stable at low temperature for a short time (...

Highly regioselective nitrile oxide dipolar cycloadditions with ortho-nitrophenyl alkynes.

The dipolar cycloadditions of ortho-nitrophenyl alkynes with aryl nitrile oxides has been demonstrated. A range of substituents are tolerated on the alkyne. These reactions proceed with excellent levels of regioselectivity. Subsequent functionalization of the isoxazole scaffold has been demonstrated.

Highly Saturated Packings and Reduced Coverings

We introduce and study certain notions which might serve as substitutes for maximum density packings and minimum density coverings. A body is a compact connected set which is the closure of its interior. A packing P with congruent replicas of a body K is n-saturated if no n− 1 members of it can be replaced with n replicas of K, and it is completely saturated if it is n-saturated for each n ≥ 1....

A Highly Tunable Silicone-Based Magnetic Elastomer with Nanoscale Homogeneity.

Magnetic elastomers have been widely pursued for sensing and actuation applications. Silicone-based magnetic elastomers have a number of advantages over other materials such as hydrogels, but aggregation of magnetic nanoparticles within silicones is difficult to prevent. Aggregation inherently limits the minimum size of fabricated structures and leads to non-uniform response from structure to s...