Highly Nonstoichiometric YAG Ceramics with Modified Luminescence Properties

نویسندگان

چکیده

Y3Al5O12 (YAG) is a widely used phosphor host. Its optical properties are controlled by chemical substitution at its YO8 or AlO6/AlO4 sublattices, with emission wavelengths defined rare-earth and transition-metal dopants that have been explored extensively. Nonstoichiometric compositions Y3+xAl5-xO12 (x ≠ 0) may offer route to new distributing over two more sublattices simultaneously, producing local coordination environments for the activator ions. However, YAG typically behaves as line phase, such therefore challenging synthesize. Here, series of highly nonstoichiometric 0 ≤ x 0.40 reported, corresponding ≤20% AlO6 sublattice substituted Y3+, synthesized advanced melt-quenching techniques. This impacts up-conversion luminescence Yb3+/Er3+-doped systems, whose yellow-green differs from red-orange their stoichiometric counterparts. In contrast, YAG:Ce3+ system has different structural response nonstoichiometry down-conversion only weakly affected. Analogous systems should be obtainable range garnet materials, demonstrated here synthesis Gd3.2Al4.8O12 Gd3.2Ga4.8O12. opens pathways property tuning control host stoichiometry, prospect improved performance applications garnet-type materials.

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ژورنال

عنوان ژورنال: Advanced Functional Materials

سال: 2023

ISSN: ['1616-301X', '1616-3028']

DOI: https://doi.org/10.1002/adfm.202213418