High-Pressure Spectral Studies of Mixed Valence Compounds of Antimony
نویسندگان
چکیده
منابع مشابه
High-pressure spectral studies of mixed valence compounds of antimony.
In Cs(2)SbCl(6) and related compounds antimony appears as Sb(III) and Sb(V) in alternate halide octahedra. The optical spectrum contains "mixed valence" peaks assigned to Sb(III) --> Sb(V) transfer near 18 and 27 kK (cm(-1)). In addition there is a peak near 31 kK assigned to an internal transition on Sb(III) and one near 37 kK assigned to Sb(V), mixed with the absorption edge of the crystal. T...
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ژورنال
عنوان ژورنال: Proceedings of the National Academy of Sciences
سال: 1973
ISSN: 0027-8424,1091-6490
DOI: 10.1073/pnas.70.11.3065