High Generation Dendrimers via Thiol-Michael Click Chemistry
نویسندگان
چکیده
منابع مشابه
Degradable dendrimers divergently synthesized via click chemistry.
Large degradable dendrimers (MW > 30 kDA) were synthesized in a divergent manner utilizing a novel 1,3,5-triazaadamantane (TAA) monomer that can degrade under acidic conditions.
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Dendrimers up to the fourth generation were successfully prepared via the divergent growth strategy using a combination of thiol-ene "click" chemistry and traditional esterification reactions. The thiol-ene reactions were conducted under solvent-free, ambient conditions at room temperature by irradiating with UV light. The fourth-generation dendrimers were subsequently functionalized with carbo...
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Freestanding substrates with high refractive index modulation, good oxygen resistance, and low volume shrinkage are critical in photolithography for the purpose of high density data storage, image patterning and anticounterfeiting. Herein, we demonstrate a novel paradigm of direct holographic image patterning via the radical-mediated thiol− yne click reaction subsequent to the base-catalyzed th...
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Unsymmetrical dendrimers, containing both mannose binding units and coumarin fluorescent units, have been prepared using click chemistry and shown to be highly efficient, dual-purpose recognition/detection agents for the inhibition of hemagglutination.
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Orthogonal, sequential “click” reactions were implemented to yield novel polymeric substrates with the ability to record holographic data. The base-catalyzed thiol−acrylate Michael “click” reaction was implemented to yield a writable, stage 1 polymeric substrate with glass transition temperatures (Tg) ranging from 0 to −26 °C and rubbery storage moduli (E′) from 11.1 to 0.3 MPa. The loosely cro...
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ژورنال
عنوان ژورنال: Biophysical Journal
سال: 2014
ISSN: 0006-3495
DOI: 10.1016/j.bpj.2013.11.2359