Hierarchical MOF-xerogel monolith composites from embedding MIL-100(Fe,Cr) and MIL-101(Cr) in resorcinol-formaldehyde xerogels for water adsorption applications

Programming MIL-101Cr for selective and enhanced CO2 adsorption at low pressure by postsynthetic amine functionalization.

MIL-101Cr fully or partially (p) postsynthetically modified with nitro (-NO2) or amino (-NH2) groups was shown to be a robust, water stable, selective and enhanced carbon dioxide (CO2) adsorption material with the amine-functionality. The highly microporous amine-modified frameworks (up to 1.6 cm(3) g(-1) total pore volume) exhibit excellent thermal stability (>300 °C) with BET surface areas up...

MOF derived composites for cathode protection: coatings of LiCoO2 from UiO-66 and MIL-53 as ultra-stable cathodes.

A mechanochemical synthetic method of preparing LiCoO2 coated by MOF-derived metal oxide composites is introduced. Mono-dispersed ZrO2 and Al2O3 are applied as protection layers. These composites show 148 mA h g(-1) at a current density of 2325 mA g(-1) and excellent thermal stability (55 °C).

The cc., c.cm., MIL., mil., and ml.

The cc., c.cm., MIL., mil., and ml.

[This corrects the article on p. 281 in vol. 83.].

The Preparation of Porous Sol-Gel Silica with Metal Organic Framework MIL-101(Cr) by Microwave-Assisted Hydrothermal Method for Adsorption Chillers

Abstract: Metal organic framework (MOF) of MIL-101(Cr)-Silica (SiO₂) composites with highly mesoporous and uniform dispersions were synthesized by a microwave-assisted hydrothermal method followed by the sol-gel technique. Water vapor adsorption experiments were conducted on the MIL-101(Cr)-SiO₂ composites for industrial adsorption chiller applications. The effects of MIL-101(Cr)-SiO₂ mixing ra...