Heteronuclear Bimetallic Complexes with 3d and 4f Elements
نویسندگان
چکیده
Three heteronuclear bimetallic complexes [Cu(MeOH)(L)Ln(NO3)3] (1-Ce; Ln = Ce, 1-Pr; Pr, and 1-Nd; Nd) were prepared using H2L (1,3-bis[(3-methoxysalicylidene)amino]-2,2-dimethylpropane) in methanol, affording the as green crystalline materials. These can be a one-pot synthesis from 2,2-dimethylpropan-1,3-diamine, o-vanillin, copper(II) nitrate, Ln(III) nitrate (Ln Nd). X-ray crystallography, high-resolution mass spectrometry, UV-vis spectroscopy used to characterize complexes. All three showed copper center adopting five-coordinate square pyramidal geometry lanthanoid cation ten-coordinate geometry.
منابع مشابه
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ژورنال
عنوان ژورنال: Molbank
سال: 2023
ISSN: ['1422-8599']
DOI: https://doi.org/10.3390/m1577