Heterogeneous Reactions of Epoxides in Acidic Media
نویسندگان
چکیده
منابع مشابه
Heterogeneous reactions of epoxides in acidic media.
Epoxides have recently been identified as important intermediates in the gas phase oxidation of hydrocarbons, and their hydrolysis products have been observed in ambient aerosols. To evaluate the role of epoxides in the formation of secondary organic aerosols (SOA), the kinetics and mechanism of heterogeneous reactions of two model epoxides, isoprene oxide and α-pinene oxide, with sulfuric acid...
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A copper-catalyzed cross-coupling reaction of epoxides with arylboronates is described. This reaction is not limited to aromatic epoxides, because aliphatic epoxides are also suitable substrates. In addition, N-sulfonyl aziridines can be successfully converted into the products. This reaction provides convenient access to β-phenethyl alcohols, which are valuable synthetic intermediates.
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ژورنال
عنوان ژورنال: The Journal of Physical Chemistry A
سال: 2012
ISSN: 1089-5639,1520-5215
DOI: 10.1021/jp2112704