Hemidirected novel lead(II) azide complex of 2,6-diacetylpyridine dihydrazone
نویسندگان
چکیده
منابع مشابه
Crystal structure of 1,1-diacetylferrocene dihydrazone
The title compound, [Fe(C7H9N2)2], crystallizes with two crystallographically independent mol-ecules in the unit cell. These represent the chiral atropoisomers distinguished by the mutual arrangement of the two acet-yl-hydrazone groups with a cis conformation of the C=N bonds. The two cyclo-penta-dienyl (Cp) rings are planar and nearly parallel, the tilt between the two rings being 3.16 (16)° [...
متن کاملSynthesis and in Vitro Antimicrobial Activity of Novel Series of 3,5-diacetylpyridine Compounds.
Bis diacetylpyridine derivative (1) was prepared and reacted with different halo-compounds, namely: epichlorohydrine and dichloroethyl ethyl ether to give 2a,b, respectively, and reacted with morpholine and piperidine to afford Mannich products 3a,b, successively. Compound 4 was synthesized by reaction of 1 with potassium thiocyanate. Reaction of 4 with 4-chlorobenzaldehyde, glucose and phthali...
متن کاملElectrocatalytic Azide Oxidation Mediated by a Rh(PNP) Pincer Complex
One-electron oxidation of the rhodium(I) azido complex [Rh(N3 )(PNP)] (5), bearing the neutral, pyridine-based PNP ligand 2,6-bis(di-tert-butylphosphinomethyl)pyridine, leads to instantaneous and selective formation of the mononuclear rhodium(I) dinitrogen complex [Rh(N2 )(PNP)]+ (9+ ). Interestingly, complex 5 also acts as a catalyst for electrochemical N3- oxidation (Ep ≈-0.23 V vs. Fc+/0 ) i...
متن کاملTHE CYTOCHROME c-AZIDE COMPLEX BY B. L. HORECKER
Since both cyanide and azide have been shown to block the oxidation of cytochrome c by cytochrome oxidase (l), it has been generally accepted that the toxicity of these substances is due to this property. A considerable amount of evidence has accumulated, however, indicating that aside and cyanide do not inhibit respiration in a parallel manner under all conditions. Thus Stannard (2) was able t...
متن کاملDNA-binding and cleavage studies of a novel two-dimensional manganese(II) azide complex with N-methylimidazole.
A new complex, manganese(II) azide complex with N-methylimidazole, has been synthesized and characterized by elemental analysis, IR spectra and single crystal X-ray studies. Absorption spectroscopy, emission spectroscopy, viscosity measurements and CD spectroscopy have been used to investigate the binding of the complex with calf thymus DNA (CTDNA). The intrinsic binding constant K(b) of the co...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Acta Crystallographica Section A Foundations of Crystallography
سال: 2008
ISSN: 0108-7673
DOI: 10.1107/s0108767308086637