HEATS OF HYDROLYSIS OF AMIDE AND PEPTIDE BONDS
نویسندگان
چکیده
منابع مشابه
Heats of hydrolysis of amide and peptide bonds.
The thermodynamics of amide and peptide bonds is of fundamental importance in the study of the synthesis and breakdown of proteins in biological systems. One of the necessary steps in acquiring significant thermodynamic data in this field is the determination of the changes in heat content accompanying the formation or rupture of such bonds in compounds of known structure. We have accordingly u...
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In an accompanying paper, Dobry and Sturtevant (1) have outlined a calorimetric procedure by which the heats of hydrolysis of amides and peptides can be determined. Application of this method to a hydrolysis for which the equilibrium can be determined is of considerable interest, since it then becomes possible to evaluate directly, for the first time, the thermodynamic functions pertinent to su...
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DNA catalysts (deoxyribozymes) for a variety of reactions have been identified by in vitro selection. However, for certain reactions this identification has not been achieved. One important example is DNA-catalyzed amide hydrolysis, for which a previous selection experiment instead led to DNA-catalyzed DNA phosphodiester hydrolysis. Subsequent efforts in which the selection strategy deliberatel...
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ژورنال
عنوان ژورنال: Journal of Biological Chemistry
سال: 1952
ISSN: 0021-9258
DOI: 10.1016/s0021-9258(19)50882-1