Halogen Bonds of Iodonium Ions: A World Dissimilar to Silver Coordination
نویسندگان
چکیده
A distinct difference between the three-center halogen bond and analogous coordinative of silver is demonstrated by computational, X-ray crystallographic solution NMR spectroscopic investigations their complexes with a bidentate Lewis base. Iodine(I) preferentially forms an entropically favored monomeric complex, whereas silver(I) enthalpically dimeric complexes. Counterion coordination considerably influences structure in solid state, it does not have notable effect on bond. transition metals metal
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ژورنال
عنوان ژورنال: Bulletin of the Chemical Society of Japan
سال: 2021
ISSN: ['1348-0634', '0009-2673']
DOI: https://doi.org/10.1246/bcsj.20200274