Green Hydrophilic Capsules from Cellulose Nanocrystal-Stabilized Pickering Emulsion Polymerization: Morphology Control and Spongelike Behavior
نویسندگان
چکیده
Pickering inverse emulsions of hydroxyl oligoethylene glycol methacrylate were stabilized in isopropyl myristate, a biofriendly oil, using surface-modified cellulose nanocrystals (CNCs) as stabilizing particles. The further polymerized by free or controlled radical polymerization (ATRP), taking advantage the bromoisobutyrate functions grafted on CNC surface. Suspension emulsion led to full bead empty capsule morphologies, depending initiation locus. thickness shell surrounding could be tuned modulating aggregation state CNCs after their surface modification. An increase from 6 40 layers helped improve compression moduli beads dozen hundreds kPa.
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ژورنال
عنوان ژورنال: Biomacromolecules
سال: 2021
ISSN: ['1525-7797', '1526-4602']
DOI: https://doi.org/10.1021/acs.biomac.1c00581