Grain boundary dynamics in ceramics superplasticity
نویسندگان
چکیده
منابع مشابه
Grain boundary segregation in oxide ceramics
D PR O Abstract The factors which control grain boundary segregation in oxide ceramics are reviewed. These include grain boundary energy, cation–cation interactions, impurity cation size, as well as electrostatic interactions with the grain boundary space charge. In addition, an approach for measuring grain boundary segregation in those materials, as a function of the five macroscopic parameter...
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Ceramics exhibit macroscopic stressistrain rate relations that should lead to superplastic extension. However, premature fracture is normally encountered, due to the formation and growth of grain-boundary cavities. Thus, cavity nucleation and growth were analyzed in an attempt to identify microstructures and/or strain-rate regimes that would suppress cavity evolution and hence allow superplasti...
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A~~act-Semi~uantitative Auger Electron Spectroscopy (AES) on pure monophasic (Z~*)~.~(YO,.~~,,, was used to determine the chemical composition of the grain boundaries. Grain boundary enrichment with Y was observed with an enrichment factor of about 1.5. The difference in activation energy of the ionic conductivity of the grain boundary compared with the bulk can be explained by the Y segregatio...
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The dynamics of dislocation-free crystal facets is examined in the context of grain boundary grooves at the junction between two crystallites of a solid and the liquid phase. The geometry and thermal conditions of grain boundary grooves allow a detailed analysis of facet morphology during solidification in terms of the nucleation and spreading rates of elementary crystal planes. Observations on...
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ژورنال
عنوان ژورنال: Revista de Metalurgia
سال: 2001
ISSN: 1988-4222,0034-8570
DOI: 10.3989/revmetalm.2001.v37.i2.487