Glass Transition of Cellulose Derivatives

Affinity and its derivatives in the glass transition process.

The thermodynamic treatment of the glass transition remains an issue of intense debate. When associated with the formalism of non-equilibrium thermodynamics, the lattice-hole theory of liquids can provide new insight in this direction, as has been shown by Schmelzer and Gutzow [J. Chem. Phys. 125, 184511 (2006)], by Möller et al. [J. Chem. Phys. 125, 094505 (2006)], and more recently by Tropin ...

Functionalization of Cellulose: Synthesis of Water-soluble Cationic Cellulose Derivatives

One of the trends of modern cellulose chemistry is the functionalization of known cellulose derivatives in order to expand their application area. In this work, water-soluble cationic cellulose derivatives containing up to 4% coupled nitrogen were obtained by the amination of hydroxyethylcellulose (HEC) with two different etherification agents, diethylepoxypropylamine (DEEPA) and (2-chlorethyl)...

Influence of hydrogen bonds on glass transition and dielectric relaxations of cellulose

The molecular dynamic in hydrated cellulose has been investigated by a combination of thermal analyses and dielectric spectroscopy. Differential Scanning Calorimetry (DSC) shows the dependence upon hydration of the glass transition temperature Tg. A physical ageing phenomenon has been observed. At the molecular scale, bound water is hydrogen bonded to polar sites of cellulose macromolecules. At...

Application of Cellulose and Cellulose Derivatives in Pharmaceutical Industries

Size Exclusion Chromatography of Cellulose and Cellulose Derivatives

Approximately 2 X 10 ton biomass is produced on land and in water annually (l). Cellulose is the principal structural material in the cell wall of all plants (2). In addition, cellulose can be found in algae, bacteria, and animals (tunicates). Assuming that the average source contains 50% cellulose (Table 1) (35), then approximately 1 X 10 ton cellulose is formed each year. This makes cellulose...