Gas hydrates at high pressure

High-pressure gas hydrates.

It has long been known that crystalline hydrates are formed by many simple gases that do not interact strongly with water, and in most cases the gas molecules or atoms occupy 'cages' formed by a framework of water molecules. The majority of these gas hydrates adopt one of two cubic cage structures and are called clathrate hydrates. Notable exceptions are hydrogen and helium which form 'exotic' ...

P 01 High - pressure gas hydrates

Many simple gases that do not interact strongly with water form crystalline hydrates in which the gas molecules or atoms occupy ‘cages’ formed by a framework of water molecules. These clathrate hydrates are stabilised by hydrophobic gas-water interactions and are model systems for the study of these interactions. Many gas hydrates also occur in nature and their properties provide a basis for mo...

High-pressure transformations in xenon hydrates.

A high-pressure investigation of the Xe*H(2)O chemical system was conducted by using diamond-anvil cell techniques combined with in situ Raman spectroscopy, synchrotron x-ray diffraction, and laser heating. Structure I xenon clathrate was observed to be stable up to 1.8 GPa, at which pressure it transforms to a new Xe clathrate phase stable up to 2.5 GPa before breaking down to ice VII plus sol...

7 Natural Gas Hydrates

Natural Gas Hydrates

Sir Humphry Davy witnessed the first chlorine hydrate crystallizing in 1811. Couple of century later his discovery, natural gas hydrates has begun to play an important role in energy business. From being a mere chemical curiosity, they have proven to be a nuisance for the natural gas industry. The problem of hydrate induced blockage in “wet gas” flow systems has been widely reported and became ...