Functional Conducting Polymers via Thiol-ene Chemistry
نویسندگان
چکیده
منابع مشابه
Functional Conducting Polymers via Thiol-ene Chemistry
We demonstrate here that thiol-ene chemistry can be used to provide side-chain functionalized monomers based on 3,4-propylenedioxythiophene (ProDOT) containing ionic, neutral, hydrophobic, and hydrophilic side chains. All reactions gave high yields and purification could generally be accomplished through precipitation. These monomers were polymerized either chemically or electro-chemically to g...
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Towards the development of (bio)degradable polymers with medical relevance a non-radical thiolene synthesis route is investigated. In this work, step growth polymerization based on Michael addition click reactions is presented. Homotelechelic RAFT polymers were conjugated leading to polymers with molar weight distribution typical for a step growth polymerization, tailing up to 100 000 g∙mol-1 i...
متن کاملPost-functionalization of ATRP polymers using both thiol/ene and thiol/disulfide exchange chemistry.
In this communication, we report on a new route to the functionalization of ATRP polymers exploiting their halide end-groups, which were converted successfully into reactive disulfide end-groups, using sodium methanethiosulfonate. The resultant disulfide-terminated polymers could then be reacted with different functional thiols to yield functional polymers exploiting either thiol/disulfide exch...
متن کاملThe Power of Thiol-ene Chemistry
As a tribute to Professor Charlie Hoyle, we take the opportunity to review the impact of thiol-ene chemistry on polymer and materials science over the past 5 years. During this time, a renaissance in thiol-ene chemistry has occurred with recent progress demonstrating its unique advantages when compared with traditional coupling and functionalization strategies. Additionally, the robust nature o...
متن کاملFunctional Microcapsules via Thiol-Ene Photopolymerization in Droplet-Based Microfluidics.
Thiol-ene chemistry was exploited in droplet-based microfluidics to fabricate advanced microcapsules with tunable encapsulation, degradation, and thermal properties. In addition, by utilizing the thiol-ene photopolymerization with tunable cross-link density, we demonstrate the importance of monomer conversion on the retention of omniphilic cargo in double emulsion templated microcapsules. Furth...
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ژورنال
عنوان ژورنال: Biosensors
سال: 2012
ISSN: 2079-6374
DOI: 10.3390/bios2030305