Formation and structural chemistry of the unusual cyanide-bridged dinuclear species [Ru2(NN)2(CN)7]3− (NN=2,2′-bipyridine or 1,10-phenanthroline)
نویسندگان
چکیده
منابع مشابه
Synthesis of Binuclear Monohydroxo Bridged Copper(II) Complexes with 1,10-Phenanthroline and 4,4'-Dimethyl-2,2'-Bipyridine
Tow new compound of type [(chelate)2Cu-OH-Cu(chelate)2] X3.nH2O, where chelate=1,10-phenanthroline; X=Cl¯(n=3.5) and chelate=4,4'-dimethyl-2,2'-bipyridine; (n=5) have been synthesized and their properties investigated. The complexes show room temperature magnetic moment order of 1.0 B.M. per copper atom. The X-band ESR spectrum of powdered sample...
متن کاملsynthesis of binuclear monohydroxo bridged copper(ii) complexes with 1,10-phenanthroline and 4,4'-dimethyl-2,2'-bipyridine
tow new compound of type [(chelate)2cu-oh-cu(chelate)2] x3.nh2o, where chelate=1,10-phenanthroline; x=cl¯(n=3.5) and chelate=4,4'-dimethyl-2,2'-bipyridine; (n=5) have been synthesized and their properties investigated. the complexes show room temperature magnetic moment order of 1.0 b.m. per copper atom. the x-band esr spectrum of powdered samples at room temperature shows typical dm=1 transit...
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15 صفحه اولSynthesis, spectral and redox switchable cubic NLO properties of chiral dinuclear iron cyanide/isocyanide-bridged complexes.
Two chiral dinuclear cyanide/isocyanide-bridged complexes (R)-[Cp(dppe)Fe-CN-Fe(dppp)Cp]PF6 (1[PF6]) and (R)-[Cp(dppe)Fe-NC-Fe(dppp)Cp]PF6 (2[PF6]), and their mono-oxidation products (R)-[Cp(dppe)Fe(II)-CN-Fe(III)(dppp)Cp] [PF6]2 (1[PF6]2) and (R)-[Cp(dppe)Fe(III)-NC-Fe(II)(dppp)Cp][PF6]2 (2[PF6]2) were synthesized and fully characterized. The electronic spectra of both the mixed-valence comple...
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ژورنال
عنوان ژورنال: Inorganica Chimica Acta
سال: 2009
ISSN: 0020-1693
DOI: 10.1016/j.ica.2008.06.017