Flavobacterium heparinum 3-O-sulphatase for N-substituted glucosamine 3-O-sulphate
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Aqua(3-fluorobenzoato-κO)(3-fluorobenzoato-κ2 O,O′)(1,10-phenanthroline-κ2 N,N′)cobalt(II)
In the title compound, [Co(C(7)H(4)FO(2))(2)(C(12)H(8)N(2))(H(2)O)], the Co(II) ion is coordinated by two O atoms from one 3-fluoro-benzoate (fb) ligand and one O atom from another fb ligand, two N atoms from the 1,10-phenanthroline ligand and a water mol-ecule in a distorted octa-hedral geometry. An intra-molecular O-H⋯O hydrogen bond occurs. Inter-molecular O-H⋯O hydrogen bonds link pairs of ...
متن کامل[N,N′-Bis(3-methoxy-2-oxidobenzylidene)ethylenediammonium-κ4 O,O′,O′′,O′′′]tris(nitrato-κ2 O,O′)dysprosium(III)
In the title mononuclear Schiff base complex, [Dy(NO(3))(3)(C(18)H(20)N(2)O(4))], the Dy(III) ion is ten-coordinated in a distorted hexa-deca-hedral geometry by six O atoms of three nitrate anions and four O atoms of the Schiff base ligand. An intra-molecular N-H⋯O hydrogen bond occurs. The crystal structure is stabilized by inter-molecular C-H⋯O hydrogen bonds.
متن کاملBis(μ-3-carboxy-2-oxidobenzoato)-κ3O1,O 2:O 3;κ3 O 3:O1,O 2-bis[aqua(2,2′-bipyridine-κ2 N,N′)copper(II)]
In the centrosymmetric dinuclear complex, [Cu(2)(C(8)H(4)O(5))(2)(C(10)H(8)N(2))(2)(H(2)O)(2)], the Cu(II) ion is coordinated by two N atoms from a bipyridine ligand, three O atoms from two 3-carb-oxy-2-oxidobenzoate dianions and the O atom of the water mol-ecule in a distorted octa-hedral geometry. The Cu--O(H) coordination [2.931 (3) Å] is very weak. In the crystal structure, the dinuclear un...
متن کاملPoly[(5,5′-dimethyl-2,2′-bipyridine-κ2 N,N′)(μ3-5-hydroxyisophthalato-κ4 O 1:O 3,O 3′:O 3′)cadmium]
In the title compound, [Cd(C(8)H(4)O(5))(C(12)H(12)N(2))], the Cd(II) cation is coordinated by three 5-hy-droxy-isophthalate anions and one 5,5'-bimethyl-2,2'-bipyridine ligand in a distorted CdO(4)N(2) octa-hedral geometry. The 5-hy-droxy-isophthalate anions bridge the Cd cations, forming a two-dimensional polymeric complex parallel to (100). In the complex, the hy-droxy group is linked to the...
متن کاملcatena-Poly[[diaquacadmium(II)]bis(μ-2,2-dimethylbutanedioato-κ4 O,O′:O′′,O′′′)[diaquacadmium(II)]-μ-1,4-bis(3-pyridylmethyl)piperazine-κ2 N 3:N 3′]
In the title compound, [Cd(2)(C(6)H(8)O(4))(2)(C(16)H(20)N(4))(H(2)O)(4)](n), penta-gonal-bipyramidally coordinated Cd(II) ions are connected into {Cd(2)(2,2-dimethyl-succinate)(2)(H(2)O)(4)} centrosymmetric dimeric clusters. In turn, these clusters are linked by tethering 1,4-bis-(3-pyridylmeth-yl)piperazine (3-bpmp) ligands into [Cd(2)(2,2-dimethyl-succinate)(2)(3-bpmp)(H(2)O)(4)](n) coordina...
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ژورنال
عنوان ژورنال: European Journal of Biochemistry
سال: 1985
ISSN: 0014-2956,1432-1033
DOI: 10.1111/j.1432-1033.1985.tb08847.x