Faster with fluorine
نویسندگان
چکیده
منابع مشابه
Modulating NHC catalysis with fluorine
Fluorination often confers a range of advantages in modulating the conformation and reactivity of small molecule organocatalysts. By strategically introducing fluorine substituents, as part of a β-fluoroamine motif, in a triazolium pre-catalyst, it was possible to modulate the behaviour of the corresponding N-heterocyclic carbene (NHC) with minimal steric alterations to the catalyst core. In th...
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ژورنال
عنوان ژورنال: Nature Nanotechnology
سال: 2007
ISSN: 1748-3387,1748-3395
DOI: 10.1038/nnano.2007.304