Faster transport in hollow zeolites

Facile synthesis of nano-sized hollow single crystal zeolites under mild conditions.

We report a method to synthesize hollow ZSM-5 single crystals of a size below 100 nm that could function as nanoreactors with access through the zeolite micropores only. In the first step, ZSM-5 is synthesized with the respective crystal size. In the second, the zeolite is base leached and acid washed under mild conditions.

Faster and more accurate transport procedures for HZETRN

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Enantioselective adsorption in achiral zeolites.

Cationic motion in dehydrated zeolites

The exchangeable cations in dehydrated zeolites, types X and Y, are located on several energetically and coordinatively different sites. The number of vacant sites is of the same orde; of magnitude as the number of occupied sites. As a result, the motions of the cations as evidenced by the dielectric relaxation and electrical conductivity, are highly correlated. The dielectric relaxation can be...

Mesostructured zeolites: bridging the gap between zeolites and MCM-41.

Surfactant-templating is one of the most versatile and useful techniques to implement mesoporous systems into solid materials. Various strategies based on various interactions between surfactants and solid precursors have been explored to produce new structures. Zeolites are invaluable as size- and shape-selective solid acid catalysts. Nevertheless, their micropores impose limitations on the ma...