Factors Controlling β-Elimination Reactions in Group 10 Metal Complexes
نویسندگان
چکیده
منابع مشابه
Metal-Metal Bonding in Uranium-Group 10 Complexes.
Heterobimetallic complexes containing short uranium-group 10 metal bonds have been prepared from monometallic IU(IV)(OAr(P)-κ(2)O,P)3 (2) {[Ar(P)O](-) = 2-tert-butyl-4-methyl-6-(diphenylphosphino)phenolate}. The U-M bond in IU(IV)(μ-OAr(P)-1κ(1)O,2κ(1)P)3M(0), M = Ni (3-Ni), Pd (3-Pd), and Pt (3-Pt), has been investigated by experimental and DFT computational methods. Comparisons of 3-Ni with t...
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Three components, one pot synthesis of thiasalen/selenasalen Ni(II), Pd(II) and Pt(II) complexes, 14-19, by the oxidative addition of S-S/Se-Se bond of bis(o-formylphenyl)disulfide/-diselenide to Ni(0), Pd(0) and Pt(0) followed by in situ Schiff base formation with ethylenediamine is reported. S-S or Se-Se bonds were cleaved and coordinated to the metal center as thiolate (ArS(-)) or selenolate...
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ژورنال
عنوان ژورنال: Chemistry - A European Journal
سال: 2015
ISSN: 0947-6539
DOI: 10.1002/chem.201502769