ExoMol line lists – XLI. High-temperature molecular line lists for the alkali metal hydroxides KOH and NaOH
نویسندگان
چکیده
Potassium hydroxide (KOH) and sodium (NaOH) are expected to occur in the atmospheres of hot rocky super-Earth exoplanets but a lack spectroscopic data is hampering their potential detection. Using robust first-principles methodologies, comprehensive molecular line lists for KOH NaOH that applicable temperatures up $T=3500$ K presented. The OYT4 list covers 0-6000 cm$^{-1}$ (wavelengths $\lambda > 1.67$ $\mu$m) range comprises 38 billion transitions between 7.3 million energy levels with rotational excitation $J=255$. OYT5 0 - 9000 1.11$ contains almost 50 lines involving 7.9 states $J=206$. available from ExoMol database at www.exomol.com should greatly aid study exoplanets.
منابع مشابه
ExoMol line lists – XVIII. The high-temperature spectrum of VO
An accurate line list, VOMYT, of spectroscopic transitions is presented for hot VO. The 13 lowest electronic states are considered. Curves and couplings are based on initial ab initio electronic structure calculations and then tuned using available experimental data. Dipole moment curves, used to obtain transition intensities, are computed using high levels of theory (e.g. MRCI/aug-cc-pVQZ usin...
متن کاملExoMol: molecular line lists for exoplanet and other atmospheres
The discovery of extrasolar planets is one of the major scientific advances of the last two decades. Hundreds of planets have now been detected and astronomers are beginning to characterize their composition and physical characteristics. To do this requires a huge quantity of spectroscopic data most of which are not available from laboratory studies. The ExoMol project will offer a comprehensiv...
متن کاملExoMol molecular line lists XIX : high - accuracy computed hot line lists for H 218 O and H 217
Hot line lists for two isotopologues of water, H2O and H2O, are presented. The calculations employ newly constructed potential energy surfaces (PES), which take advantage of a novel method for using the large set of experimental energy levels for H2O to give high-quality predictions for H2O and H2O. This procedure greatly extends the energy range for which a PES can be accurately determined, al...
متن کاملExoMol line lists – III. An improved hot rotation-vibration line list for HCN and HNC
A revised rotation-vibration line list for the combined hydrogen cyanide (HCN)/hydrogen isocyanide (HNC) system is presented. The line list uses ab initio transition intensities calculated previously and extensive data sets of recently measured experimental energy levels. The resulting line list has significantly more accurate wavelengths than previous ones for these systems. An improved value ...
متن کاملExoMol molecular line lists – XVII . The rotation – vibration spectrum of hot SO 3
Sulphur trioxide (SO3) is a trace species in the atmospheres of the Earth and Venus, as well as being an industrial product and an environmental pollutant. A variational line list for SO3, named UYT2, is presented containing 21 billion vibration–rotation transitions. UYT2 can be used to model infrared spectra of SO3 at wavelengths longwards of 2 μm (ν < 5000 cm−1) for temperatures up to 800 K. ...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Monthly Notices of the Royal Astronomical Society
سال: 2021
ISSN: ['0035-8711', '1365-8711', '1365-2966']
DOI: https://doi.org/10.1093/mnras/staa4041