exo-Selective Peripheral Cycloaddition Reactions of Pyrido[2,1-a]isoindole
نویسندگان
چکیده
منابع مشابه
Catalytic asymmetric exo-selective [6+3] cycloaddition of iminoesters with fulvenes.
A novel exo-selective [6+3] cycloaddition approach for the highly enantioselective synthesis of polysubstituted piperidines was developed. The developed methodology was applied in a one-pot [6+3]-[4+2] dicycloaddition, allowing the construction of structurally and stereochemically rich polycyclic compounds from simple building blocks.
متن کاملCu(I)-catalyzed highly exo-selective and enantioselective [3 + 2] cycloaddition of azomethine ylides with acrylates.
[reaction: see text] A novel Cu(I)-catalyzed asymmetric 1,3-dipolar cycloaddition of azomethine ylides with acrylates has been developed. Up to 98/2 exo/endo selectivity and up to 98% enantiomeric excess have been achieved.
متن کاملCycloaddition reactions of unsaturated sulfones
The reaction of a series of allyl-substituted bis(phenylsulfony1)methanes or dimethyl malonates with 2,3-bis(phenylsulfonyl)l13-butadiene in the presence of base afforded alkenyl-substituted allenes in good yield. The reaction proceeds by initial attack of the soft carbanion onto the terminal position of the diene and subsequent PhS02elimination to give the phenylsulfonyl substituted allene. Th...
متن کاملComputational study of cycloaddition reactions
Cycloaddition reactions between 1,3-butadiene and the C-terminated SiC(1 0 0)-c(2 · 2) surface have been addressed using quantum-chemical methods. The c(2 · 2) structure consists of ACBCA bridges between underlayer Si atoms which themselves form SiASi bonds. Of various possible reaction products, the one formed by a [2+ 4] reaction with the ACBCA bridge (giving a species resembling 1,4-cyclohex...
متن کاملTheoretical studies on cycloaddition reactions
Cycloaddition reactions represent one of the most powerful processes in organic chemistry. The most common types of cycloaddition reactions are the Diels-Alder (DA) and the 1,3-dipolar cycloaddition reactions (1,3-DCs) which lead to five and six membered rings, respectively. In our ongoing efforts to contribute to the understanding of DA and 1,3-DCs; we studied the following using the B3LYP/6-3...
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ژورنال
عنوان ژورنال: Bulletin of the Chemical Society of Japan
سال: 1985
ISSN: 0009-2673,1348-0634
DOI: 10.1246/bcsj.58.3547