Exact and Optimal Quantum Mechanics/Molecular Mechanics Boundaries

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Exact and Optimal Quantum Mechanics/Molecular Mechanics Boundaries.

Motivated by recent work in density matrix embedding theory, we define exact link orbitals that capture all quantum mechanical (QM) effects across arbitrary quantum mechanics/molecular mechanics (QM/MM) boundaries. Exact link orbitals are rigorously defined from the full QM solution, and their number is equal to the number of orbitals in the primary QM region. Truncating the exact set yields a ...

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ژورنال

عنوان ژورنال: Journal of Chemical Theory and Computation

سال: 2014

ISSN: 1549-9618,1549-9626

DOI: 10.1021/ct500512f