Ex-LDH-Based Catalysts for CO2 Conversion to Methanol and Dimethyl Ether

نویسندگان

چکیده

CO2-derived methanol and dimethyl ether can play a very important role as fuels, energy carriers, bulk chemicals. Methanol production from CO2 renewable hydrogen is considered to be one of the most promising pathways alleviate global warming. In turn, could subsequently dehydrated into DME; alternatively, one-step conversion DME obtained by hydrogenation on bifunctional catalysts. this light, four oxide catalysts with same Cu Zn content (Cu/Zn molar ratio = 2) were synthesized calcining corresponding CuZnAl LDH systems modified Zr and/or Ce. The fresh ex-LDH characterized in terms composition, texture, structure, surface acidity basicity, reducibility. Structural acid–base properties also studied H2-treated samples, which specific metal area dispersion metallic determined well. After situ H2 treatment, tested for at 250 °C 3.0 MPa. experimental conditions, was physically mixing acid ferrierite or ZSM-5 zeolites. For both processes, effect Al/Zr/Ce products distribution investigated.

برای دانلود باید عضویت طلایی داشته باشید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Hollow alumina nanospheres as novel catalyst for the conversion of methanol to dimethyl ether

This paper investigates hollow and porous alumina nanospheres that were previously synthesized to be used for the dehydration of methanol to dimethyl ether (DME). As hollow nanostructures possess characteristics such as low density and high surface to volume ratio, their catalytic activity between hollow and porous structure is compared. For this purpose, three most important parameters (acidit...

متن کامل

hollow alumina nanospheres as novel catalyst for the conversion of methanol to dimethyl ether

this paper investigates hollow and porous alumina nanospheres that were previously synthesized to be used for the dehydration of methanol to dimethyl ether (dme). as hollow nanostructures possess characteristics such as low density and high surface to volume ratio, their catalytic activity between hollow and porous structure is compared. for this purpose, three most important parameters (acidit...

متن کامل

A Hierarchically Micro-Meso-Macroporous Zeolite CaA for Methanol Conversion to Dimethyl Ether

A hierarchical zeolite CaA with microporous, mesoporous and macroporous structure was hydrothermally synthesized by a ”Bond-Blocking” method using organo-functionalized mesoporous silica (MS) as a silica source. The characterization by XRD, SEM/TEM and N2 adsorption/desorption techniques showed that the prepared material had well-crystalline zeolite Linde Type A (LTA) topological structure, mic...

متن کامل

Selective homogeneous and heterogeneous catalytic conversion of methanol/dimethyl ether to triptane.

The demand for specific fuels and chemical feed-stocks fluctuates, and as a result, logistical mismatches can occur in the supply of their precursor raw materials such as coal, biomass, crude oil, and methane. To overcome these challenges, industry requires a versatile and robust suite of conversion technologies, many of which are mediated by synthesis gas (CO + H(2)) or methanol/dimethyl ether...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

ژورنال

عنوان ژورنال: Catalysts

سال: 2021

ISSN: ['2073-4344']

DOI: https://doi.org/10.3390/catal11050615